The kinetics of activation of RX by a Cu(I) complex has been investigated in MeCN both in the absence and presence of halide ions. The system Cu(I)/L/X (L = Me6TREN) is mainly composed of Cu(I)L+, XCu(I)L and Cu(I)X2-, but only Cu(I)L+ is found to be an active catalyst reacting with RX.
New insights into the mechanism of activation of atom transfer radical polymerization by Cu(I) complexes
AHMED ISSE, ABDIRISAK;BORTOLAMEI, NICOLA;GENNARO, ARMANDO
2011
Abstract
The kinetics of activation of RX by a Cu(I) complex has been investigated in MeCN both in the absence and presence of halide ions. The system Cu(I)/L/X (L = Me6TREN) is mainly composed of Cu(I)L+, XCu(I)L and Cu(I)X2-, but only Cu(I)L+ is found to be an active catalyst reacting with RX.
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