The decomposition of carbon suboxide in the presence of two rhodium(I)-complexes leads to CO and C2O. With (PPh3)3RhCl, (1) and polymeric C2O are formed, with [(C8H14)2RhCl]2 the polymers (2) and cyclooctene. Pyridine can “dissolve” the Cl-bridge in (2); a dimer is formed.
Reactions of Carbon Suboxide with Rhodium(I) Complexes
PANDOLFO, LUCIANO
1981
Abstract
The decomposition of carbon suboxide in the presence of two rhodium(I)-complexes leads to CO and C2O. With (PPh3)3RhCl, (1) and polymeric C2O are formed, with [(C8H14)2RhCl]2 the polymers (2) and cyclooctene. Pyridine can “dissolve” the Cl-bridge in (2); a dimer is formed.
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